The Reauthentication Dialog for passwords has been enabled by default last week in chromium and after Mac OS¹, this feature is now ported over Windows in the last chromium build as you can see in this screenshot below.

As you might expect, clicking on the "Show" action at chrome://settings/passwords will prompt you to reauthenticate with your Windows Account to reveal the plain password.

¹ https://plus.google.com/+FrancoisBeaufort/posts/2zhYDGP822Z

Source: https://codereview.chromium.org/34393007
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